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There are various tools in the research world, but little real world use.

Isabelle/HOL - Coq competitor like GCC and LLVM (http://www.cl.cam.ac.uk/research/hvg/Isabelle/)

ATS - C with proof assistant (http://www.ats-lang.org/)

KeY - Java with verification annotations (http://www.key-project.org/)



Interestingly, HOL Light is used to prove that the density of a packing of congruent spheres in three dimensions is never greater than pi/sqrt(18), a 400 year old problem:

https://code.google.com/p/flyspeck/wiki/FlyspeckFactSheet

300,000 lines of code, still unfinished.




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