Isabelle/HOL - Coq competitor like GCC and LLVM (http://www.cl.cam.ac.uk/research/hvg/Isabelle/)
ATS - C with proof assistant (http://www.ats-lang.org/)
KeY - Java with verification annotations (http://www.key-project.org/)
https://code.google.com/p/flyspeck/wiki/FlyspeckFactSheet
300,000 lines of code, still unfinished.
Isabelle/HOL - Coq competitor like GCC and LLVM (http://www.cl.cam.ac.uk/research/hvg/Isabelle/)
ATS - C with proof assistant (http://www.ats-lang.org/)
KeY - Java with verification annotations (http://www.key-project.org/)